.
Element |
|
Symbol |
Bi |
Element name |
Bismuth |
Periodic table row |
Row 6 |
Periodic table column |
Column ⅢA |
Atomic number |
83 |
Atomic weight |
209 kg/kmol |
Date of discovery ("-" = BCE) |
1500 |
Group |
Other metals |
Electronic Structure |
||
Electronic structure |
[Xe] 4f14 5d10 6s2 6p3 |
|
Valence |
5 |
|
First ionization energy |
7.29 eV |
|
Second ionization energy |
16.7 eV |
|
Electronegativity (Pauling) |
2.02 |
|
Fig2: Crystal structure
|
||
Physical property |
||
Density at 300K |
9.75 kg/ |
|
Mechanical properties |
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Young's modulus at 300K |
34 GPa |
|
Shear modulus at 300K |
13.1 GPa |
|
Bulk modulus at 300K |
31.5 GPa |
|
Poisson's ratio |
0.33 GPa |
|
Diffusion data |
||
Pre-exponential, lattice self-diffusion |
2.26 |
|
Activation energy, lattice self-diffusion |
130 kJ/mol |
|
Surface energies |
||
Surface energy, liquid |
0.378 J/ |
|
Magnetic properties |
||
Magnetic classification |
Diamagnetic |
|
Magnetic susceptibility |
-16.5 |
|
|
|
|
Critical material information |
||
In EU Critical list? |
||
In US Critical list? |
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Abundance risk level |
High |
|
Environmental country risk Herfindahl-Hirschman Index (HHI) |
3.67 |
|
Environmental country risk level |
High |
|
Sourcing and geopolitical risk Herfindahl-Hirschman Index (HHI |
4 |
|
Sourcing and geopolitical risk level |
Very high |
|
Price volatility |
66.5 % |
|
Price volatility risk |
Very low |
Crystal structure |
||
Crystal structure |
Rhombohedra |
|
Space group |
R3m |
|
Lattice parameter, a |
0.455 nm |
|
Lattice parameter, c |
1.190 nm |
|
Atomic radius |
0.155 nm |
|
Atomic volume |
35.6e-30 |
|
Molar volume |
21.4e-3 |
|
State at 300K (Metal / Non-metal) |
Metal |
|
Phase at 300K (Solid / Liquid / Gas) |
Solid |
|
Thermal properties |
||
Melting temperature |
271 °C |
|
Boiling point |
1.61e3 °C |
|
Heat of fusion |
11.3 kJ/mol |
|
Heat of vaporization |
209 kJ/mol |
|
Cohesive energy |
210 kJ/mol |
|
Thermal expansion coefficient at 300K |
13.4 μstrain/°C |
|
Specific heat capacity |
120 J/kg.°C |
|
Debye temperature |
-154 °C |
|
Thermal conductivity at 300K |
7.87 W/m.°C |
|
Nuclear properties |
||
Neutron absorption cross section (0.025 eV) |
33 Barns |
|
Neutron scattering cross section (0.025 eV) |
9 Barns |
|
Binding energy per nucleon |
7.85 keV |
|
Geo-economic data |
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Typical exploited ore grade |
0.424 % |
|
Minimum economic ore grade |
0.2 % |
|
Abundance in the Earth's crust |
37.9e-3 ppm |
|
Abundance in seawater |
89.4e-6 ppm |
|
Annual world production |
10.2e3 tonne/yr |
|
World reserves |
320e3 tonne |
|
Main mining data (metric tonnes / yr) |
||
Bolivia, 10 Canada, 50 China, 6.5 Mexico, 940 Other countries, 90 |
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Principal uses and substitutes
35% used in fusible alloys, solders and ammunition cartridges, including use in wires, safety fuses and molded
Alternative: lead. Quality: good.
35% used in metallurgical additives for automobiles, planes, grip tubes, tools and Alternative: lead. Quality: adequate.
28% used in pharmaceuticals, particularly Alternative: magnesium compounds. Quality: good.
2% other uses, including pigments, dentistry, glass, enameled ceramics and plastic Alternative: N/A.